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Dibromido(2,9-dimethyl-1,10-phenanthroline-?(2) N,N')(dimethyl sulfoxide-?O)cadmium.


ABSTRACT: In the mol-ecule of the title compound, [CdBr2(C14H12N2)(C2H6OS)], the Cd(II) atom is five-coordinated in a distorted trigonal-bipyramidal configuration by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand, one O atom from a dimethyl sulfoxide ligand and two Br atoms. In the crystal, ?-? contacts between the pyridine and benzene rings [centroid-centroid distances = 3.710?(5), 3.711?(6) and 3.627?(5)?Å] stabilize the structure.

SUBMITTER: Moghanlou K 

PROVIDER: S-EPMC3588265 | biostudies-literature | 2013 Jan

REPOSITORIES: biostudies-literature

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Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N')(dimethyl sulfoxide-κO)cadmium.

Moghanlou Khadijeh K  

Acta crystallographica. Section E, Structure reports online 20121212 Pt 1


In the mol-ecule of the title compound, [CdBr2(C14H12N2)(C2H6OS)], the Cd(II) atom is five-coordinated in a distorted trigonal-bipyramidal configuration by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand, one O atom from a dimethyl sulfoxide ligand and two Br atoms. In the crystal, π-π contacts between the pyridine and benzene rings [centroid-centroid distances = 3.710 (5), 3.711 (6) and 3.627 (5) Å] stabilize the structure. ...[more]

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