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Dibromido(2,9-dimethyl-1,10-phenanthroline-?(2)N,N')zinc.

ABSTRACT: The reaction of equimolar amounts of zinc bromide and 2,9-dimethyl-1,10-phenanthroline in dry methanol provided the title compound, [ZnBr(2)(C(14)H(12)N(2))], in good yield. The Zn(II) ion is coordinated in a distorted tetra-hedral environment by two N atoms from the chelating 2,9-dimethyl-1,10-phenanthroline ligand and two bromide ions. There is inter-molecular ?-? stacking between adjacent phenanthroline units, with centroid-centroid distances of 3.594?(3) and 3.652?(3)?Å.

SUBMITTER: Dehghani A

PROVIDER: S-EPMC3379135 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2)N,N')zinc.

Dehghani Ali A M Amini Mostafa M Najafi Ezzatollah E Tadjarodi Azadeh A Notash Behrouz B

Acta crystallographica. Section E, Structure reports online 20120526 Pt 6

The reaction of equimolar amounts of zinc bromide and 2,9-dimethyl-1,10-phenanthroline in dry methanol provided the title compound, [ZnBr(2)(C(14)H(12)N(2))], in good yield. The Zn(II) ion is coordinated in a distorted tetra-hedral environment by two N atoms from the chelating 2,9-dimethyl-1,10-phenanthroline ligand and two bromide ions. There is inter-molecular π-π stacking between adjacent phenanthroline units, with centroid-centroid distances of 3.594 (3) and 3.652 (3) Å. ...[more]

PMID: 22719356

Similar Datasets

Dibromido(2,9-dimethyl-1,10-phenanthroline-?N,N')cadmium.

Project description:In the title complex, [CdBr(2)(C(14)H(12)N(2))], the Cd(II) ion is tetra-coordinated by two N atoms of the bidentate 2,9-dimethyl-1,10-phenanthroline ligand and two bromide ions in a substanti-ally distorted CdN(2)Br(2) tetra-hedral geometry. In the crystal, inversion dimers linked by pairs of weak C-H?Br bonds generate R(2) (2)(14) loops. Aromatic ?-? stacking [shortest centroid-centroid separation = 3.633?(2)?Å] inter-actions occur within, and also link, the dimers into chains propagating parallel to [100].

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Project description:In the asymmetric unit of the title complex, [Mn(C(7)H(5)O(3))(2)(C(14)H(12)N(2))(H(2)O)]·0.5C(14)H(12)N(2), the Mn(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) mol-ecule, one water mol-ecule and two monodentate 2-hydroxy-benzoate anions in a distorted trigonal-bipyramidal geometry. The OH group of the 2-hydroxy-benzoate anion is disordered over two positions with site-occupancy factors of 0.5. The asymmetric unit is completed with by an uncoordinated half-mol-ecule of dmphen, disordered about a crystallographic twofold axis. In the crystal structure, mol-ecules are linked into a two-dimensional framework by O-H?N, O-H?O and C-H?O hydrogen bonds. The packing of the structure is further stabilized by ?-? stacking inter-actions involving dmphen mol-ecules, with centroid-centroid separations of 3.8027?(3) and 3.6319?(3)?Å.

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Dibromido(2,9-dimethyl-1,10-phenanthroline-?(2)N,N')cobalt(II) acetonitrile monosolvate.

Project description:In the title compound, [CoBr(2)(C(14)H(12)N(2))]·CH(3)CN, the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a chelating 2,9-dimethyl-1,10-phenanthroline ligand and two terminal Br atoms. In the crystal, ?-? contacts between the pyridine and benzene rings [centroid-centroid distances = 3.828?(5), 3.782?(5), 3.880?(5) and 3.646?(5)?Å] stabilize the structure.

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Dichlorido(2,9-dimethyl-1,10-phenanthroline)manganese(II) hemihydrate.

Project description:In the title compound, [MnCl(2)(C(14)H(12)N(2))]·0.5H(2)O, all of the non-H atoms apart from the Cl atom lie on a mirror plane and the methyl H atoms are disordered over two sites of equal occupancy about the mirror plane. The Mn(II) ion is coordinated in a distorted tetra-hedral environment by two N atoms of the phenanthroline ligand and two chloride ions. A half-occupancy solvent water mol-ecule lies on a mirror plane and close to an inversion center.

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Aqua-(2,9-dimethyl-1,10-phenanthroline-?N,N')bis-(3-hydroxy-benzoato-?O)manganese(II)-2,9-dimethyl-1,10-phenanthroline-water (1/1/1).

Project description:In the title compound, [Mn(C(7)H(5)O(3))(2)(C(14)H(12)N(2))(H(2)O)]·C(14)H(12)N(2)·H(2)O, the Mn(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, two monodentate 3-hydroxy-benzoate anions (3-HBA) and one water mol-ecule in a distorted trigonal-bipyramidal environment. An uncoordinated dmphen and an uncoordinated water mol-ecule cocrystallized with each complex mol-ecule. Intra- and inter-molecular O-H?N and O-H?O hydrogen bonds are also present between the coordinated 3-HBA and water mol-ecules and the uncoordinated dmphen and water mol-ecules in the crystal. The packing of the structure is further stabilized by ?-? stacking inter-actions involving dmphen mol-ecules, with a centroid-centroid separation of 3.705?(3)?Å.

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Dichlorido(2,9-dimethyl-1,10-phenanthroline-?N,N')cobalt(II).

Project description:In the title compound, [CoCl(2)(C(14)H(12)N(2))], the Co(II) atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand and two Cl atoms. The Co atom and the phenanthroline unit are located on a mirror plane. The methyl H atoms are disordered about the mirror plane and areeach half-occupied. In the crystal structure, ?-? inter-actions between the pyridine and benzene rings and between the pyridine rings [centroid-centroid distances = 3.8821?(9) and 3.9502?(10)?Å, respectively] stabilize the structure.

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Dichlorido(2,9-dimethyl-1,10-phenanthroline-?N,N')copper(II).

Project description:In the title compound, [CuCl(2)(C(14)H(12)N(2))], the complex molecule has m symmetry, with the mirror plane oriented parallel to the planar molecule and the ligated Cu(II) atom. The metal centre has a distorted tetra-hedral coordination formed by two N atoms from one 2,9-dimethyl-1,10-phenanthroline ligand and two Cl atoms. There is inter-molecular ?-? stacking between adjacent 2,9-dimethyl-1,10-phenanthroline ligands, with a centroid-centroid distance of 3.733?(2)Å.

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