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Bis(ethanamidinium) (1,10-phen-an-thro-line-2,9-dicarboxyl-ato)manganate(II) hepta-hydrate.

ABSTRACT: In the title complex, (C2H7N2)2[Mn(C14H6N2O4)2]·7H2O, the Mn(II) atom is coordinated by four N atoms and four O atoms from two 1,10-phenanthroline-2,9-dicarboxyl-ate ligands in a distorted dodeca-hedral geometry. The double negative charge is balanced by two ethanamidinium cations. A three-dimensional supra-molecular structure is formed through N-H?O and O-H?O hydrogen bonds and ?-? stacking inter-actions [centroid-centroid distance = 3.553?(2)?Å].

SUBMITTER: Miao YL

PROVIDER: S-EPMC3588374 | biostudies-literature | 2013 Jan

REPOSITORIES: biostudies-literature

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Bis(ethanamidinium) (1,10-phen-an-thro-line-2,9-dicarboxyl-ato)manganate(II) hepta-hydrate.

Miao Yan-Li YL Wang Hong-Bo HB Song Wen-Dong WD

Acta crystallographica. Section E, Structure reports online 20121205 Pt 1

In the title complex, (C2H7N2)2[Mn(C14H6N2O4)2]·7H2O, the Mn(II) atom is coordinated by four N atoms and four O atoms from two 1,10-phenanthroline-2,9-dicarboxyl-ate ligands in a distorted dodeca-hedral geometry. The double negative charge is balanced by two ethanamidinium cations. A three-dimensional supra-molecular structure is formed through N-H⋯O and O-H⋯O hydrogen bonds and π-π stacking inter-actions [centroid-centroid distance = 3.553 (2) Å]. ...[more]

PMID: 23476314

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