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ABSTRACT:
SUBMITTER: Zhu G
PROVIDER: S-EPMC3588491 | biostudies-literature | 2013 Mar
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20130220 Pt 3
In the title complex, [Co(C15H12BrClNO)2], the Co(II) ion is coordinated by two N,O-bidentate 2-bromo-4-chloro-6-[(E)-(2,6-dimethyl-phen-yl)imino-meth-yl]phenolate ligands, generating a squashed CoN2O2 tetra-hedral coordination geometry. The dihedral angles between the aromatic rings in the ligands are 82.60 (14) and 71.79 (14)°. The complex has approximate local noncrystallographic twofold symmetry. In the crystal, weak aromatic π-π stacking is observed [centroid-centroid separation = 3.6434 (1 ...[more]