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Bis{2-bromo-4-chloro-6-[(E)-(2,6-di-methyl-phen-yl)imino-meth-yl]phenolato-?(2) N,O}cobalt(II).

ABSTRACT: In the title complex, [Co(C15H12BrClNO)2], the Co(II) ion is coordinated by two N,O-bidentate 2-bromo-4-chloro-6-[(E)-(2,6-dimethyl-phen-yl)imino-meth-yl]phenolate ligands, generating a squashed CoN2O2 tetra-hedral coordination geometry. The dihedral angles between the aromatic rings in the ligands are 82.60?(14) and 71.79?(14)°. The complex has approximate local noncrystallographic twofold symmetry. In the crystal, weak aromatic ?-? stacking is observed [centroid-centroid separation = 3.6434?(18)?Å].

SUBMITTER: Zhu G

PROVIDER: S-EPMC3588491 | biostudies-literature | 2013 Mar

REPOSITORIES: biostudies-literature

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Bis{2-bromo-4-chloro-6-[(E)-(2,6-di-methyl-phen-yl)imino-meth-yl]phenolato-κ(2) N,O}cobalt(II).

Zhu Gang G Jiao Bao-Juan BJ

Acta crystallographica. Section E, Structure reports online 20130220 Pt 3

In the title complex, [Co(C15H12BrClNO)2], the Co(II) ion is coordinated by two N,O-bidentate 2-bromo-4-chloro-6-[(E)-(2,6-dimethyl-phen-yl)imino-meth-yl]phenolate ligands, generating a squashed CoN2O2 tetra-hedral coordination geometry. The dihedral angles between the aromatic rings in the ligands are 82.60 (14) and 71.79 (14)°. The complex has approximate local noncrystallographic twofold symmetry. In the crystal, weak aromatic π-π stacking is observed [centroid-centroid separation = 3.6434 (1 ...[more]

PMID: 23476501

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