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Trans-Bis[1,2-bis-(diphenyl-phosphan-yl)ethane]-chlorido(ethyn-yl)ruthenium(II).

ABSTRACT: The mol-ecular structure of the title compound, trans-[Cu(C2H)Cl(C26H24P2)2], consists of an Ru(II) cation, located on an inversion centre, in an octa-hedral environment defined by two chelating phosphines, one acetyl-ide and one chloride ligand. The -C CH and the chlorine ligands are disordered over two equivalent positions (0.5 occupancy each). The coordination geometry is distorted octa-hedral, with the -C CH fragment and the Cl ligand in trans positions. The four P atoms occupy the equatorial plane of the octa-hedron and the chloride and acetyl-ide ligands the axial positions.

SUBMITTER: Trujillo A 

PROVIDER: S-EPMC3588712 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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trans-Bis[1,2-bis-(diphenyl-phosphan-yl)ethane]-chlorido(ethyn-yl)ruthenium(II).

Trujillo Alexander A   Fuentealba Mauricio M   Arratia-Perez Ramiro R   Howard Judith A K JA  

Acta crystallographica. Section E, Structure reports online 20121103 Pt 12

The mol-ecular structure of the title compound, trans-[Cu(C2H)Cl(C26H24P2)2], consists of an Ru(II) cation, located on an inversion centre, in an octa-hedral environment defined by two chelating phosphines, one acetyl-ide and one chloride ligand. The -C CH and the chlorine ligands are disordered over two equivalent positions (0.5 occupancy each). The coordination geometry is distorted octa-hedral, with the -C CH fragment and the Cl ligand in trans positions. The four P atoms occupy the equatoria  ...[more]

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