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Azido-[1,2-bis-(diphenyl-phosphan-yl)ethane-?P,P'](?-inden-yl)ruthenium(II).

ABSTRACT: Facile ligand substitution is observed when the ruthenium chloride complex [Ru(?(5)-C(9)H(7))Cl(dppe)] (dppe is diphenylphosphanyl ethane) is treated with NaN(3) in refluxing ethanol, yielding the title compound, [Ru(?(5)-C(9)H(7))(N(3))(dppe)] or [Ru(C(9)H(7))(N(3))(C(26)H(24)P(2))]. The Ru(II) atom has a typical piano-stool coordination. The Ru-P bond lengths are 2.284?(2) and 2.235?(2)?Å. NMR and MS analyses are in agreement with the structure of the title compound.

SUBMITTER: Sung HL

PROVIDER: S-EPMC3050413 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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Azido-[1,2-bis-(diphenyl-phosphan-yl)ethane-κP,P'](η-inden-yl)ruthenium(II).

Sung Hui-Ling HL Hsu Hsiu-Ling HL Kuo Ting-Shen TS

Acta crystallographica. Section E, Structure reports online 20101224 Pt 1

Facile ligand substitution is observed when the ruthenium chloride complex [Ru(η(5)-C(9)H(7))Cl(dppe)] (dppe is diphenylphosphanyl ethane) is treated with NaN(3) in refluxing ethanol, yielding the title compound, [Ru(η(5)-C(9)H(7))(N(3))(dppe)] or [Ru(C(9)H(7))(N(3))(C(26)H(24)P(2))]. The Ru(II) atom has a typical piano-stool coordination. The Ru-P bond lengths are 2.284 (2) and 2.235 (2) Å. NMR and MS analyses are in agreement with the structure of the title compound. ...[more]

PMID: 21522535

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