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(2-Amino-ethane-thiol-ato-?(2)N,S)bis-[1,2-bis-(diphenyl-phosphan-yl)ethane-?(2)P,P']ruthenium(II) hexa-fluoridophosphate.

ABSTRACT: In the crystal of the title compound, [Ru(C(2)H(6)NS)(C(26)H(24)P(2))(2)]PF(6), the Ru(II) atom is in a slightly distorted octa-hedral geometry, coordinated by one 2-amino-ethane-thiol-ate (aet) and two 1,2-bis-(diphenyl-phosphan-yl)ethane (dppe) ligands. The crystal consists of a pair of enanti-omers (? and ?) of the compound. The ? and ? isomers have the ? and ? conformations for the aet chelate rings and the ? and ? conformations for the dppe chelate rings. The F atoms of the PF(6) (-) counter-anion are disordered over three positions, with site occupancies of 0.4, 0.3 and 0.3.

SUBMITTER: Igashira-Kamiyama A

PROVIDER: S-EPMC3515165 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

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(2-Amino-ethane-thiol-ato-κ(2)N,S)bis-[1,2-bis-(diphenyl-phosphan-yl)ethane-κ(2)P,P']ruthenium(II) hexa-fluoridophosphate.

Igashira-Kamiyama Asako A Tamura Motoshi M Konno Takumi T

Acta crystallographica. Section E, Structure reports online 20121031 Pt 11

In the crystal of the title compound, [Ru(C(2)H(6)NS)(C(26)H(24)P(2))(2)]PF(6), the Ru(II) atom is in a slightly distorted octa-hedral geometry, coordinated by one 2-amino-ethane-thiol-ate (aet) and two 1,2-bis-(diphenyl-phosphan-yl)ethane (dppe) ligands. The crystal consists of a pair of enanti-omers (Δ and Λ) of the compound. The Δ and Λ isomers have the λ and δ conformations for the aet chelate rings and the δ and λ conformations for the dppe chelate rings. The F atoms of the PF(6) (-) counte ...[more]

PMID: 23284392

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