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Cis-Bis{(E)-2-[(2-fluoro-phen-yl)imino-meth-yl]phenolato-?(2) N,O}bis-(pyridine-?N)nickel(II).

ABSTRACT: The structure of the title compound, [Ni(C13H9FNO)2(C5H5N)2], consists of an Ni(II) atom on a crystallographic center of symmetry, octa-hedrally bonded through both the N and O atoms to two 2-[(2-fluoro-phen-yl)imino-meth-yl]phenolate (L) ligands, as well as two pyridine ligands. The F atoms of L are disordered over two positions related by a 180° rotation of the fluoro-phenyl group around its external C-N bond.

SUBMITTER: Souza MC 

PROVIDER: S-EPMC3588732 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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cis-Bis{(E)-2-[(2-fluoro-phen-yl)imino-meth-yl]phenolato-κ(2) N,O}bis-(pyridine-κN)nickel(II).

Souza Marcela C G MC   Ferreira Leonardo da C Lda C   Comerlato Nadia M NM   Ferreira Glaucio B GB   Visentin Lorenzo do Canto Ldo C  

Acta crystallographica. Section E, Structure reports online 20121110 Pt 12

The structure of the title compound, [Ni(C13H9FNO)2(C5H5N)2], consists of an Ni(II) atom on a crystallographic center of symmetry, octa-hedrally bonded through both the N and O atoms to two 2-[(2-fluoro-phen-yl)imino-meth-yl]phenolate (L) ligands, as well as two pyridine ligands. The F atoms of L are disordered over two positions related by a 180° rotation of the fluoro-phenyl group around its external C-N bond. ...[more]

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