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Di-?-bromido-bis-[bromido(4,7-diphenyl-1,10-phenanthroline-?(2) N,N')cadmium].

ABSTRACT: The title compound, [Cd2Br4(C24H16N2)2], consists of a centrosymmetric dimeric unit in which two Br atoms bridge two Cd(II) atoms, forming a four-membered ring. A terminal Br atom and a bidentate chelating 4,7-diphenyl-1,10-phenanthroline ligand complete a square-pyramidal geometry for the Cd(II) atom. In the crystal, C-H?Br hydrogen bonds and ?-? contacts between the pyridine and phenyl rings [centroid-centroid distances = 3.704?(4) and 3.715?(4)?Å] lead to a three-dimensional supra-molecular structure.

SUBMITTER: Shirvan SA

PROVIDER: S-EPMC3588733 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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Di-μ-bromido-bis-[bromido(4,7-diphenyl-1,10-phenanthroline-κ(2) N,N')cadmium].

Shirvan Sadif A SA Haydari Dezfuli Sara S Khazali Fereydoon F Aghajeri Manouchehr M Borsalani Ali A

Acta crystallographica. Section E, Structure reports online 20121110 Pt 12

The title compound, [Cd2Br4(C24H16N2)2], consists of a centrosymmetric dimeric unit in which two Br atoms bridge two Cd(II) atoms, forming a four-membered ring. A terminal Br atom and a bidentate chelating 4,7-diphenyl-1,10-phenanthroline ligand complete a square-pyramidal geometry for the Cd(II) atom. In the crystal, C-H⋯Br hydrogen bonds and π-π contacts between the pyridine and phenyl rings [centroid-centroid distances = 3.704 (4) and 3.715 (4) Å] lead to a three-dimensional supra-molecular s ...[more]

PMID: 23468698

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