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Di-?-chlorido-bis-[chlorido(1,10-phenanthroline-?N,N')zinc(II)].

ABSTRACT: In the crystal structure of the title complex, [Zn(2)Cl(4)(C(12)H(8)N(2))(2)], each of the two five-coordinated Zn(II) atoms displays a strongly distorted trigonal-bipyramidal geometry defined by two N atoms from the chelate ligand and by one terminal and two bridging chloride anions. The crystal structure is stabilized by C-H?Cl inter-actions. There is inter-molecular ?-? stacking between adjacent phenanthroline ligands, with a centroid-centroid distance of 3.151?(3)?Å.

SUBMITTER: Yang XM

PROVIDER: S-EPMC2977612 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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Di-μ-chlorido-bis-[chlorido(1,10-phenanthroline-κN,N')zinc(II)].

Yang Xiao-Mao XM Leng Qing-Bo QB Chen Yi Y He You-Gang YG Luo Shi-Wu SW

Acta crystallographica. Section E, Structure reports online 20090425 Pt 5

In the crystal structure of the title complex, [Zn(2)Cl(4)(C(12)H(8)N(2))(2)], each of the two five-coordinated Zn(II) atoms displays a strongly distorted trigonal-bipyramidal geometry defined by two N atoms from the chelate ligand and by one terminal and two bridging chloride anions. The crystal structure is stabilized by C-H⋯Cl inter-actions. There is inter-molecular π-π stacking between adjacent phenanthroline ligands, with a centroid-centroid distance of 3.151 (3) Å. ...[more]

PMID: 21583798

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