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[(R)-2,2-Bis(diphenyl-phosphan-yl)-1,1'-binaphthyl-?(2) P,P']{2-[(2R)-1,2-diamino-1-(4-meth-oxy-phen-yl)-3-methyl-but-yl]-5-meth-oxy-phenyl-?C (1)}hydrido-ruthenium(II) benzene monosolvate.

ABSTRACT: In the title complex, [Ru(C19H25N2O2)H(C44H32P2)]·C6H6, the Ru(II) ion is in a distorted octa-hedral coordination environment with the hydride H atom trans to the tertiary carbinamine N atom, giving an H-Ru-N angle of 160.8?(12)°. The equatorial sites are occupied by two P atoms, the secondary carbinamine N atom and a coordinated C atom.

SUBMITTER: Abdur-Rashid K

PROVIDER: S-EPMC3588743 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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[(R)-2,2-Bis(diphenyl-phosphan-yl)-1,1'-binaphthyl-κ(2) P,P']{2-[(2R)-1,2-diamino-1-(4-meth-oxy-phen-yl)-3-methyl-but-yl]-5-meth-oxy-phenyl-κC (1)}hydrido-ruthenium(II) benzene monosolvate.

Abdur-Rashid Kamaluddin K Lough Alan J AJ

Acta crystallographica. Section E, Structure reports online 20121117 Pt 12

In the title complex, [Ru(C19H25N2O2)H(C44H32P2)]·C6H6, the Ru(II) ion is in a distorted octa-hedral coordination environment with the hydride H atom trans to the tertiary carbinamine N atom, giving an H-Ru-N angle of 160.8 (12)°. The equatorial sites are occupied by two P atoms, the secondary carbinamine N atom and a coordinated C atom. ...[more]

PMID: 23468708

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