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Bromido({2-[2-(diphenyl-phosphan-yl)benzyl-idene]hydrazin-1-yl-idene}(4-meth-oxy-anilino)methane-thiol-ato)palladium(II) acetone monosolvate.

ABSTRACT: In the title compound, [PdBr(C(27)H(23)N(3)OPS)]·C(3)H(6)O, the coordination geometry about the Pd(II) atom is distorted square-planar, arising from the attached Br, S, P and N atoms (N and Br are trans), the maximum deviation from the plane being 0.2053?(4)?Å for the N atom. The three benzene rings attached to the P atom make dihedral angles of 69.78?(7), 87.05?(7) and 77.50?(7)° with each other. An intra-molecular C-H?N hydrogen bond forms an S(6) ring motif. In the crystal, the complex mol-ecules form infinite chains along the a-axis direction through C-H?Br inter-actions, and a C-H?O inter-action links the main mol-ecule with the acetone solvent mol-ecule.

SUBMITTER: Mokthar KA

PROVIDER: S-EPMC3393237 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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Bromido({2-[2-(diphenyl-phosphan-yl)benzyl-idene]hydrazin-1-yl-idene}(4-meth-oxy-anilino)methane-thiol-ato)palladium(II) acetone monosolvate.

Mokthar Khalisah Asilah KA Shamsuddin Mustaffa M Rosli Mohd Mustaqim MM Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20120630 Pt 7

In the title compound, [PdBr(C(27)H(23)N(3)OPS)]·C(3)H(6)O, the coordination geometry about the Pd(II) atom is distorted square-planar, arising from the attached Br, S, P and N atoms (N and Br are trans), the maximum deviation from the plane being 0.2053 (4) Å for the N atom. The three benzene rings attached to the P atom make dihedral angles of 69.78 (7), 87.05 (7) and 77.50 (7)° with each other. An intra-molecular C-H⋯N hydrogen bond forms an S(6) ring motif. In the crystal, the complex mol-ec ...[more]

PMID: 22807805

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