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Trans-Bis(benzyl-diphenyl-phosphane-?P)dichloridoplatinum(II).

ABSTRACT: In the mononuclear title compound, trans-[PtCl2(C19H17P)2], the slightly distorted square-planar coordination sphere of the Pt(II) atom is occupied by two benzyl-diphenyl-phosphane ligands and two chloride atoms in a mutually trans geometry. The effective cone angles for the two phosphane ligands are 160 and 169°. C-H?Cl inter-actions generate infinite long chains along [01-1]. Additional C-H?? and ?-? stacking interactions [centroid-centroid distance = 4.2499?(15)?Å and ring slippage = 2.386?Å] are observed.

SUBMITTER: Muller A

PROVIDER: S-EPMC3588759 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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trans-Bis(benzyl-diphenyl-phosphane-κP)dichloridoplatinum(II).

Muller Alfred A

Acta crystallographica. Section E, Structure reports online 20121124 Pt 12

In the mononuclear title compound, trans-[PtCl2(C19H17P)2], the slightly distorted square-planar coordination sphere of the Pt(II) atom is occupied by two benzyl-diphenyl-phosphane ligands and two chloride atoms in a mutually trans geometry. The effective cone angles for the two phosphane ligands are 160 and 169°. C-H⋯Cl inter-actions generate infinite long chains along [01-1]. Additional C-H⋯π and π-π stacking interactions [centroid-centroid distance = 4.2499 (15) Å and ring slippage = 2.386 Å] ...[more]

PMID: 23468724

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