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Trans-Tris(4-bromo-phen-yl)dichlorido-antimony(V).

ABSTRACT: The Sb(V) atom in the title compound, [SbCl2(C6H4Br)3], has an almost regular trigonal-bipyramidal geometry with the equatorial plane made up of three C atoms of the bromo-phenyl groups and the axial positions occupied by two Cl(-) ions in a trans configuration. In the crystal, C-H?Br hydrogen bonds link the mol-ecules into zigzag chains along the b-axis direction. Pairs of C-H?Cl hydrogen bonds further link mol-ecules into cyclic dimers with R2(2)(10) ring motifs, generating a three-dimensional network.

SUBMITTER: Qiao Y

PROVIDER: S-EPMC3588792 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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trans-Tris(4-bromo-phen-yl)dichlorido-antimony(V).

Qiao Yanling Y Jiang Jin J Cui Jichun J

Acta crystallographica. Section E, Structure reports online 20121128 Pt 12

The Sb(V) atom in the title compound, [SbCl2(C6H4Br)3], has an almost regular trigonal-bipyramidal geometry with the equatorial plane made up of three C atoms of the bromo-phenyl groups and the axial positions occupied by two Cl(-) ions in a trans configuration. In the crystal, C-H⋯Br hydrogen bonds link the mol-ecules into zigzag chains along the b-axis direction. Pairs of C-H⋯Cl hydrogen bonds further link mol-ecules into cyclic dimers with R2(2)(10) ring motifs, generating a three-dimensional ...[more]

PMID: 23468757

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