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Trans-Dichloridobis[tris-(2-methoxy-phen-yl)phosphine]palladium(II).

ABSTRACT: The structure of the title compound, [PdCl(2)(C(21)H(21)O(3)P)(2)], shows a nearly square-planar geometry for the Pd(II) atom within the Cl(2)Pd[P(PhOMe)(3)](2) ligand set. The Pd(II) atom sits on a centre of inversion and therefore the asymmetric unit contains one half-mol-ecule, i.e. half of one Pd(II) atom, one Cl atom and one tris-(2-methoxy-phen-yl)phosphine ligand.

SUBMITTER: van Blerk C

PROVIDER: S-EPMC2971166 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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trans-Dichloridobis[tris-(2-methoxy-phen-yl)phosphine]palladium(II).

van Blerk Charmaine C Holzapfel Cedric W CW

Acta crystallographica. Section E, Structure reports online 20091010 Pt 11

The structure of the title compound, [PdCl(2)(C(21)H(21)O(3)P)(2)], shows a nearly square-planar geometry for the Pd(II) atom within the Cl(2)Pd[P(PhOMe)(3)](2) ligand set. The Pd(II) atom sits on a centre of inversion and therefore the asymmetric unit contains one half-mol-ecule, i.e. half of one Pd(II) atom, one Cl atom and one tris-(2-methoxy-phen-yl)phosphine ligand. ...[more]

PMID: 21578098

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