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Bis(dicyanamido-?N)[tris-(3-amino-propyl)amine-?(4) N]nickel(II).

ABSTRACT: In the title complex, [Ni(C2N3)2(C9H24N4)], the Ni(II) atom is coordinated in a distorted octa-hedral geometry by one tris-(3-amino-prop-yl)amine (tris-apa) ligand and two dicyanamide (dca) ligands [one of them disordered in a 0.681?(19):0319?(19) ratio]. Inter-molecular N-H?N hydrogen bonds involving the N atoms of the dca anions and the tris-apa amine H atoms result in the formation of a three-dimensional network.

SUBMITTER: Luo J

PROVIDER: S-EPMC3772421 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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Bis(dicyanamido-κN)[tris-(3-amino-propyl)amine-κ(4) N]nickel(II).

Luo Jun J Zhang Xin-Rong XR Qiu Li-Juan LJ Yang Feng F Liu Bao-Shu BS

Acta crystallographica. Section E, Structure reports online 20130615 Pt 7

In the title complex, [Ni(C2N3)2(C9H24N4)], the Ni(II) atom is coordinated in a distorted octa-hedral geometry by one tris-(3-amino-prop-yl)amine (tris-apa) ligand and two dicyanamide (dca) ligands [one of them disordered in a 0.681 (19):0319 (19) ratio]. Inter-molecular N-H⋯N hydrogen bonds involving the N atoms of the dca anions and the tris-apa amine H atoms result in the formation of a three-dimensional network. ...[more]

PMID: 24046564

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