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Catena-Poly[(S)-2-methyl-piperazine-1,4-diium [[trichloridobismuthate(III)]-di-?-chlorido]].

ABSTRACT: In the crystal structure of the title compound, {(C(5)H(14)N(2))[BiCl(5)]}(n), the Bi(III) cation is coordinated by six Cl(-) anions in a distorted octa-hedral geometry. Two Cl(-) anions bridge neighboring Bi(III) cations, forming a zigzag polymeric chain along the a axis. The discrete methylpiperazinediium cation adopts a normal chair conformation and is linked to the polymeric chains by N-H?Cl hydrogen bonding.

SUBMITTER: Ru ZL

PROVIDER: S-EPMC3007984 | biostudies-literature | 2010

REPOSITORIES: biostudies-literature

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catena-Poly[(S)-2-methyl-piperazine-1,4-diium [[trichloridobismuthate(III)]-di-μ-chlorido]].

Ru Zong-Ling ZL

Acta crystallographica. Section E, Structure reports online 20100811 Pt 9

In the crystal structure of the title compound, {(C(5)H(14)N(2))[BiCl(5)]}(n), the Bi(III) cation is coordinated by six Cl(-) anions in a distorted octa-hedral geometry. Two Cl(-) anions bridge neighboring Bi(III) cations, forming a zigzag polymeric chain along the a axis. The discrete methylpiperazinediium cation adopts a normal chair conformation and is linked to the polymeric chains by N-H⋯Cl hydrogen bonding. ...[more]

PMID: 21588498

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catena-Poly[[[tetra-aqua-magnesium]-trans-?-[(piperazine-1,4-diium-1,4-di-yl)bis-(methyl-ene)]di-phospho-nato] hemihydrate].

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