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N,N,N-Tri-butyl-butan-1-aminium (T-4)-(cyano-?C)tri-hydro-borate.

ABSTRACT: In the crystal structure of the title salt, C16H36N(+)·CH3BN(-), the tetra-n-butyl-ammonium cations and [BH3(CN)](-) anions are connected via weak C-H?N inter-actions, forming chains along the b-axis direction. The anion is almost linear with an N-C-B angle of 178.7?(2)°. The C-N-C angle values at the core of the tetra-n-butyl-ammonium cation range from 105.74?(11) to 111.35?(11)° with an average of 109.49?(11)°, close to the ideal tetra-hedral value.

SUBMITTER: Maris T

PROVIDER: S-EPMC3884361 | biostudies-literature | 2013 Oct

REPOSITORIES: biostudies-literature

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N,N,N-Tri-butyl-butan-1-aminium (T-4)-(cyano-κC)tri-hydro-borate.

Maris Thierry T

Acta crystallographica. Section E, Structure reports online 20131026 Pt 11

In the crystal structure of the title salt, C16H36N(+)·CH3BN(-), the tetra-n-butyl-ammonium cations and [BH3(CN)](-) anions are connected via weak C-H⋯N inter-actions, forming chains along the b-axis direction. The anion is almost linear with an N-C-B angle of 178.7 (2)°. The C-N-C angle values at the core of the tetra-n-butyl-ammonium cation range from 105.74 (11) to 111.35 (11)° with an average of 109.49 (11)°, close to the ideal tetra-hedral value. ...[more]

PMID: 24454137

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