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N,N'-Bis(phenyl-carbamo-thio-yl)benzene-1,3-dicarboxamide.

ABSTRACT: The asymmetric unit of the title compound, C22H18N4O2S2, contains two mol-ecules. In one of them, the dihedral angles between the central benzene ring and the phenyl rings are 16.97?(8) and 20.97?(8)°, while the phenyl rings make a dihedral angle of 37.87?(8)°. In the other mol-ecule, the corresponding values are 34.92?(7), 53.90?(7) and 60.68?(8)°, respectively. In each mol-ecule, two intra-molecular N-H?O hydrogen bonds generate S(6) rings and a short C-H?S contact also occurs. In the crystal, N-H?S, N-H?O, C-H?O and C-H?S inter-actions link the mol-ecules into a three-dimensional network.

SUBMITTER: Ngaini Z

PROVIDER: S-EPMC3884437 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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N,N'-Bis(phenyl-carbamo-thio-yl)benzene-1,3-dicarboxamide.

Ngaini Zainab Z Mohd Ariff Maya Asyikin MA Wan Zullkiplee Wan Sharifatun Handayani WS Hussain Hasnain H Rosli Mohd Mustaqim MM

Acta crystallographica. Section E, Structure reports online 20130803 Pt 9

The asymmetric unit of the title compound, C22H18N4O2S2, contains two mol-ecules. In one of them, the dihedral angles between the central benzene ring and the phenyl rings are 16.97 (8) and 20.97 (8)°, while the phenyl rings make a dihedral angle of 37.87 (8)°. In the other mol-ecule, the corresponding values are 34.92 (7), 53.90 (7) and 60.68 (8)°, respectively. In each mol-ecule, two intra-molecular N-H⋯O hydrogen bonds generate S(6) rings and a short C-H⋯S contact also occurs. In the crystal, ...[more]

PMID: 24427019

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