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Bis(tri-ethyl-ammonium) chloranilate.

ABSTRACT: IN THE CRYSTAL STRUCTURE OF THE TITLE COMPOUND [SYSTEMATIC NAME: bis-(tri-ethyl-ammonium) 2,5-di-chloro-3,6-dioxo-cyclo-hexa-1,4-diene-1,4-diolate], 2C6H16N(+)·C6Cl2O4 (2-), the chloranilate anion lies on an inversion center. The tri-ethyl-ammonium cations are linked on both sides of the anion via bifurcated N-H?(O,O) and weak C-H?O hydrogen bonds to give a centrosymmetric 2:1 aggregate. The 2:1 aggregates are further linked by C-H?O hydrogen bonds into a zigzag chain running along [01-1].

SUBMITTER: Gotoh K

PROVIDER: S-EPMC3884448 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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Bis(tri-ethyl-ammonium) chloranilate.

Gotoh Kazuma K Maruyama Shinpei S Ishida Hiroyuki H

Acta crystallographica. Section E, Structure reports online 20130810 Pt 9

IN THE CRYSTAL STRUCTURE OF THE TITLE COMPOUND [SYSTEMATIC NAME: bis-(tri-ethyl-ammonium) 2,5-di-chloro-3,6-dioxo-cyclo-hexa-1,4-diene-1,4-diolate], 2C6H16N(+)·C6Cl2O4 (2-), the chloranilate anion lies on an inversion center. The tri-ethyl-ammonium cations are linked on both sides of the anion via bifurcated N-H⋯(O,O) and weak C-H⋯O hydrogen bonds to give a centrosymmetric 2:1 aggregate. The 2:1 aggregates are further linked by C-H⋯O hydrogen bonds into a zigzag chain running along [01-1]. ...[more]

PMID: 24427039

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