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Bis(2-phenyl-ethyl-ammonium) tetra-chloridocobaltate(II).

ABSTRACT: Crystals of the title compound, (C(6)H(5)CH(2)CH(2)NH(3))(2)[CoCl(4)], were grown by the solvent-evaporation method. This inorganic-organic hybrid compound exhibits a layered structure in which isolated CoCl(4) inorganic layers alternate with bilayers of phenylethylammonium cations. Although the inorganic anion is zero-dimensional, the layered structure is stabilized via N-H?Cl hydrogen bonds. The CoCl(4) tetra-hedra connect to the cations through N-H?Cl hydrogen bonds, building a two-dimensional network extending parallel to (010).

SUBMITTER: Oh IH

PROVIDER: S-EPMC3089155 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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Bis(2-phenyl-ethyl-ammonium) tetra-chloridocobaltate(II).

Oh In-Hwan IH Kim Dahye D Huh Young-Duk YD Park Younbong Y Park J M Sungil JM Park Seong-Hun SH

Acta crystallographica. Section E, Structure reports online 20110407 Pt 5

Crystals of the title compound, (C(6)H(5)CH(2)CH(2)NH(3))(2)[CoCl(4)], were grown by the solvent-evaporation method. This inorganic-organic hybrid compound exhibits a layered structure in which isolated CoCl(4) inorganic layers alternate with bilayers of phenylethylammonium cations. Although the inorganic anion is zero-dimensional, the layered structure is stabilized via N-H⋯Cl hydrogen bonds. The CoCl(4) tetra-hedra connect to the cations through N-H⋯Cl hydrogen bonds, building a two-dimensiona ...[more]

PMID: 21754265

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