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N,N,N',N'-Tetra-methyl-ethylene-diammonium tetra-chlorido-zincate.

ABSTRACT: The asymmetric unit of the title compound, (C6H18N2)[ZnCl4], consists of one tetra-chlorido-zincate anion and two half-N,N,N'N'-tetra-methyl-ethylenedi-ammonium cations. Each of the two di-ammonium cations is located about an inversion center and one of them is disordered over two sets of sites in a 0.780 (17):0.220 (17) ratio. The Zn(II) atom has a slightly distorted tetra-hedral coordination environment. The cations and anions are connected via N-H⋯Cl hydrogen bonds into chains extending along [0-11].

SUBMITTER: Akhtar M

PROVIDER: S-EPMC3884984 | biostudies-literature | 2013 Nov

REPOSITORIES: biostudies-literature

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N,N,N',N'-Tetra-methyl-ethylene-diammonium tetra-chlorido-zincate.

Akhtar Muhammad M Fettouhi Mohammed M Ahmed Maqsood M Khan Islam Ullah IU Ahmad Saeed S

Acta crystallographica. Section E, Structure reports online 20131106 Pt 12

The asymmetric unit of the title compound, (C6H18N2)[ZnCl4], consists of one tetra-chlorido-zincate anion and two half-N,N,N'N'-tetra-methyl-ethylenedi-ammonium cations. Each of the two di-ammonium cations is located about an inversion center and one of them is disordered over two sets of sites in a 0.780 (17):0.220 (17) ratio. The Zn(II) atom has a slightly distorted tetra-hedral coordination environment. The cations and anions are connected via N-H⋯Cl hydrogen bonds into chains extending along ...[more]

PMID: 24454159

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