Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

N,N,N',N'-Tetra-methyl-ethylene-diammonium tetra-chloridocobaltate(II).

ABSTRACT: The asymmetric unit of the title compound, [(CH(3))(2)NH(CH(2))(2)NH(CH(3))(2)][CoCl(4)], contains a tetra-chlorido-cobalt-ate(II) dianion and two halves of two centrosymmetric, crystallographically-independent, dications. One independent dication is disordered between two conformations in a 0.784?(13):0.216?(13) ratio. In the crystal, inter-molecular N-H?Cl hydrogen bonds link cations and anions into chains propagated in [01]. These hydrogen bonds contribute to the distorted tetra-hedral geometry at the Co(II) atom.

SUBMITTER: Baughman RG

PROVIDER: S-EPMC3050123 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

N,N,N',N'-Tetra-methyl-ethylene-diammonium tetra-chloridocobaltate(II).

Baughman Russell G RG Shane Rebecca S RS McCormick James M JM

Acta crystallographica. Section E, Structure reports online 20101204 Pt 1

The asymmetric unit of the title compound, [(CH(3))(2)NH(CH(2))(2)NH(CH(3))(2)][CoCl(4)], contains a tetra-chlorido-cobalt-ate(II) dianion and two halves of two centrosymmetric, crystallographically-independent, dications. One independent dication is disordered between two conformations in a 0.784 (13):0.216 (13) ratio. In the crystal, inter-molecular N-H⋯Cl hydrogen bonds link cations and anions into chains propagated in [01]. These hydrogen bonds contribute to the distorted tetra-hedral geomet ...[more]

PMID: 21522515

Similar Datasets

N,N,N',N'-Tetra-methyl-ethylene-diammonium tetra-chlorido-zincate.

Project description:The asymmetric unit of the title compound, (C6H18N2)[ZnCl4], consists of one tetra-chlorido-zincate anion and two half-N,N,N'N'-tetra-methyl-ethylenedi-ammonium cations. Each of the two di-ammonium cations is located about an inversion center and one of them is disordered over two sets of sites in a 0.780 (17):0.220 (17) ratio. The Zn(II) atom has a slightly distorted tetra-hedral coordination environment. The cations and anions are connected via N-H⋯Cl hydrogen bonds into chains extending along [0-11].

| S-EPMC3884984 | biostudies-literature

1-Cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane tetra-chloridocobaltate(II).

Project description:In the title salt, (C(8)H(15)N(3))[CoCl(4)], the four chloride anions coordinate the Co(II) ion in a distorted tetra-hedral geometry. In the crystal, N-H?Cl hydrogen bonds link cations and anions into chains running along the c axis. The crystal packing is further stabilized by weak C-H?Cl and C-H?N inter-actions.

| S-EPMC3344387 | biostudies-literature

Bis(1-adamantylammonium) tetra-chloridocobaltate(II).

Project description:The Co(II) atom in the title salt, (C(10)H(18)N)(2)[CoCl(4)], exists in a tetra-hedral coordination geometry. The asymmetric unit has two cations that lie on different special positions of site symmetry m; the anion lies on another special position of site symmetry m.

| S-EPMC2960250 | biostudies-literature

Bis(2-phenyl-ethyl-ammonium) tetra-chloridocobaltate(II).

Project description:Crystals of the title compound, (C(6)H(5)CH(2)CH(2)NH(3))(2)[CoCl(4)], were grown by the solvent-evaporation method. This inorganic-organic hybrid compound exhibits a layered structure in which isolated CoCl(4) inorganic layers alternate with bilayers of phenylethylammonium cations. Although the inorganic anion is zero-dimensional, the layered structure is stabilized via N-H?Cl hydrogen bonds. The CoCl(4) tetra-hedra connect to the cations through N-H?Cl hydrogen bonds, building a two-dimensional network extending parallel to (010).

| S-EPMC3089155 | biostudies-literature

Bis(ethyl-enedithio)tetra-thia-fulvalenium-tetra-chloridocobaltate(II) (3/2).

Project description:The structure of the electrochemically crystallized title compound, (C(10)H(8)S(8))(3)[CoCl(4)](2), consists of two types of bis-(ethyl-enedithio)tetra-thia-fulvalene (BEDT-TTF) radical cation stacks separated by sheets of tetra-hedral [CoCl(4)](2-) anions. One of the BEDT-TTF mol-ecules is generated by inversion. There are short S⋯S contacts between the stacks in the a direction and short C-H⋯Cl contacts between the radical cations and the anions.

| S-EPMC2960064 | biostudies-literature

trans-Dichlorido-tetra-kis-[(di-methyl-phosphor-yl)methanaminium-?O]cobalt(II) tetra-chloridocobaltate(II).

Project description:The asymmetric unit of the title structure, [CoCl2(C3H11NOP)4][CoCl4]2, consists of one half of the trans-dichlorido-tetra-kis-[(di-methyl-phosphor-yl)methanaminium]cobalt(II) tetra-cation lying on an inversion center and one tetra-chloridocobaltate(II) dianion on a general position. Four O-coordinated cationic (di-methyl-phosphor-yl)methanaminium (dpmaH(+)) ligands occupy the equatorial coordination sites, whereas the chloride ligands occupy axial positions of the roughly o-cta-hedral coordination polyhedron of the cobalt metal center. Intra-molecular hydrogen bonds between the aminium groups and the O atom of the phosphoryl groups and additional hydrogen bonds between the aminium groups and the chloride ligands are present. Furthermore, four of the six H atoms not involved in intra-molecular bonding of each cobalt(II) tetra-cation form weak hydrogen bonds to four adjacent tetra-chloridocobaltate(II) counter-anions. By these inter-molecular hydrogen bonds, one-dimensional polymeric strands are formed along the b-axis direction. The hydrogen bonding is analyzed using the graph-set method and the structural similarity with dpmaHCl is discussed.

| S-EPMC3647797 | biostudies-other

Pentane-1,5-diammonium tetra-chlorido-palladate(II).

Project description:In the title compound, [NH(3)(CH(2))(5)NH(3)][PdCl(4)], the square-planar [PdCl(4)](2-) anions are centrosymmetric while the diammonium cation lies in a general position. In addition to electrostatic inter-actions, the two species are linked through N-H⋯Cl hydrogen bonds to form a three-dimensional network.

| S-EPMC2915137 | biostudies-literature

1,4,8,11-Tetra-azoniacyclo-tetra-decane tetra-chloridocobaltate(II) dichloride.

Project description:The asymmetric unit of the title compound, (C(10)H(28)N(4))[CoCl(4)]Cl(2), contains two half-mol-ecules of the macrocycle, which are both completed by crystallographic inversion symmetry. In the dianion, the Co(2+) cation is tetra-hedrally coordinated by four Cl atoms; the Co-Cl bond lengths correlate with the number of hydrogen bonds that the chloride ions accept. The crystal cohesion is supported by electrostatic inter-actions which, together with numerous N-H?Cl, N-H?(Cl,Cl) and C-H?Cl hydrogen bonds, lead to a three-dimensional network.

| S-EPMC3007426 | biostudies-other

2-Acetyl-pyridinium 3-amino-2-chloro-pyridinium tetra-chloridocobaltate(II).

Project description:In the title complex, (C(5)H(6)ClN(2))(C(7)H(8)NO)[CoCl(4)], the Co(II) ions are tetra-hedrally coordinated. The crystal structure is built from hydrogen-bonded centrosymmetric tetra-mers of tetra-chloridocobaltate(II) dianions and 3-amino-2-chloro-pyridinium cations, additionally strengthened by significant ?-? stacking of pyridinium rings [interplanar distance 3.389?(3)?Å]. The tetra-mers are linked by N-H?Cl hydrogen bonds into chains; the second kind of cations, viz. 2-acetyl-pyridinium, are connected by N-H?Cl hydrogen bonds to both sides of the chain. The Co-Cl bond lengths in the dianion correlate with the number of hydrogen bonds accepted by the Cl atom. An intramolecular C-H?Cl interaction is also present.

| S-EPMC2968359 | biostudies-literature

trans-Bis(acetonitrile-?N)tetra-aqua-cobalt(II) tetra-chloridocobaltate(II).

Project description:In the title complex, [Co(CH(3)CN)(2)(H(2)O)(4)][CoCl(4)], the Co(II) ions are octa-hedrally coordinated in the cation, with trans-disposed acetonitrile ligands, and tetra-hedrally coordinated in the anion. An extensive network of O-H(water)?Cl hydrogen bonds between cations and anions connects the ions into a three-dimensional network. The Co-Cl distances correlate with the number of hydrogen bonds accepted by the Cl atoms.

| S-EPMC2968350 | biostudies-other

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data