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[μ2-N (2),N (2')-Bis(3-meth-oxy-2-oxido-benzyl-idene)benzene-1,3-dicarbo-hydrazi-dato]bis-[pyridine-copper(II)].

ABSTRACT: In the centrosymmetric dinuclear title complex, [Cu2(C24H18N4O6)(C5H5N)2], the Cu(II) ions is tetra-coordinated by two O-atoms and one N-donor of the bridging terephthalo-hydra-zonate ligand and by one pyridine N atom, resulting in a nearly square-planar N2O2 coordination geometry with the Cu(II) ion 0.044 (2) Å out of the mean plane (r.m.s. deviation of 0.0675 Å) of the coordinating atoms.

SUBMITTER: Tong HB

PROVIDER: S-EPMC3884994 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Bis[?-4-hydr-oxy-N'-(4-meth-oxy-2-oxido-benzyl-idene)benzohydrazidato]bis-[pyridine-copper(II)].

Project description:In the title compound, [Cu(2)(C(15)H(12)N(2)O(4))(2)(C(6)H(5)N)(2)], each Cu(II) atom is chelated by the tridentate doubly deprotonated Schiff base and a pyridine mol-ecule in a nearly planar environment (r.m.s. deviation for all non-H atoms = 0.107?Å). The metal ions are bridged by one O atom from the symmetry-related Schiff base ligands, forming a centrosymmetric dinuclear copper(II) complex. The dimeric complex is linked to another dimer via weaker Cu-O inter-actions and also O-H?N hydrogen bonds.

| S-EPMC2984003 | biostudies-literature

N,N-Bis[2-(ethoxy-carbonyl-meth-oxy)-benzyl-idene]pyridine-2,6-dicarbohydrazide.

Project description:In the title compound, C(29)H(29)N(5)O(8), the ester group is disordered over two sites with site-occupancy factors of 0.91/0.09. The crystal structure is stabilized by inter- and intra-molecular hydrogen-bond inter-actions.

| S-EPMC2915248 | biostudies-literature

1,3-Bis(chloro-meth-yl)benzene.

Project description:The title compound, C8H8Cl2, used in the synthesis of many pharmaceutical inter-mediates, forms a three-dimensional network through chlorine-chlorine inter-actions in the solid-state that measure 3.513?(1) and 3.768?(3)?Å.

| S-EPMC3770413 | biostudies-literature

5-Bromo-benzene-1,3-dicarbo-nitrile.

Project description:The asymmetric unit of the title compound, C8H3BrN2, consists of two mol-ecules. The crystal structure features undulating mol-ecular sheets with the mol-ecules linked by C-H?N hydrogen bonds with one N atom acting as a bifurcated acceptor. N?Br inter-actions also occur [N?Br = 2.991?(3) and 3.099?(3)?Å]. Inter-layer association is accomplished by offset face-to-face arene inter-actions [centroid-centroid distance = 3.768?(4)?Å].

| S-EPMC3885018 | biostudies-literature

4-[(4-Meth-oxy-benzyl-idene)amino]-benzene-sulfonamide.

Project description:The title Schiff base compound, C(14)H(14)N(2)O(3)S, is non-planar, with a dihedral angle of 24.16?(7)° between the benzene rings. In the crystal, N-H?O and N-H?N hydrogen bonds link the mol-ecules into a layer parallel to (011). Intra- and inter-layer C-H?O inter-actions and ?-? inter-actions [centroid-centroid distances = 3.8900?(9) and 3.9355?(8)?Å] are also present.

| S-EPMC3379209 | biostudies-literature

(4Z,6Z)-4,6-Bis(4-meth-oxy-benzyl-idene)-2,2-dimethyl-1,3-dioxan-5-one.

Project description:The title compound, C(22)H(22)O(5), crystallizes with two independent mol-ecules in the asymmetric unit, both of which possess pseudo-C(s) symmetry. The central 1,3-dioxanone rings have envelope conformations, with the C atom bearing the two methyl groups at the flap. The benzene rings of the meth-oxy-benzyl-idene units, attached in the 4- and 6-positions on the central 1,3-dioxanone rings, are tilted in the same direction with dihedral angles varying between 8.2?(1) and 18.1?(1)°. The crystal packing is influenced by ?-stacking inter-actions of the parallel displaced type [centroid-centroid distance of 3.723?(1)?Å for mol-ecule 1 and 3.884?(1)?Å for mol-ecule 2, with ring slippages of 1.432 and 1.613?Å, respectively] and the T-shaped type, with the long mol-ecular axes all aligned along [010].

| S-EPMC3275038 | biostudies-literature

Bis[?-N'-(5-bromo-3-meth-oxy-2-oxido-benzyl-idene)-2-hydroxybenzohydra-zidato]bis[(N,N-dimethyl-formamide)-copper(II)].

Project description:The title compound, [Cu(2)(C(15)H(11)BrN(2)O(4))(2)(C(3)H(7)NO)(2)], is derived from the reaction of N'-(5-bromo-2-hy-droxy-3-meth-oxy-benzyl-idene)-2-hy-droxy-benzohydrazide and copper nitrate in a dimethyl-formamide solution in the presence of sodium hydroxide. The compound can be regarded as a binuclear centrosymmetric complex. In the crystal, the Cu(II) atom is fivefold surrounded and adopts a distorted square-pyramidal coordination environment. An intra-molecular O-H?N hydrogen bond stabilizes the mol-ecular conformation.

| S-EPMC3435625 | biostudies-literature

1,3-Bis(bromo-meth-yl)-2-nitro-benzene.

Project description:In the title compound, C(8)H(7)Br(2)NO(2), an inter-mediate for the synthesis of macrocycles, the NO(2) group makes a dihedral angle of 65.07?(19)° with the arene ring, and the bromo-methyl substituents adopt a trans conformation about the ring such that the mol-ecule closely approximates C2 symmetry.

| S-EPMC2984041 | biostudies-literature

Crystal structure of 1,3-bis-[(<i>E</i>)-4-meth-oxy-benzyl-idene-amino]-propan-2-ol.

Project description:The title Schiff base, C19H22N2O3, was synthesized via the condensation reaction of 1,3-di-amino-propan-2-ol with 4-meth-oxy-benzaldehyde using water as solvent. The mol-ecule exists in an E,E conformation with respect to the C=N imine bonds and the dihedral angle between the aromatic rings is 37.25?(15)°. In the crystal, O-H?N hydrogen bonds link the mol-ecules into infinite C(5) chains propagating along the a-axis direction. The packing of these chains is consolidated by C-H?O inter-actions and C-H?? short contacts, forming a three-dimensional network.

| S-EPMC5137596 | biostudies-literature

N,N'-Bis(4-methyl-benzyl-idene)benzene-1,4-diamine.

Project description:The centrosymmetric title compound, C(22)H(20)N(2), crystallizes with one half-mol-ecule in the asymmetric unit. The dihedral angle between the central and outer benzene rings is 46.2?(2)°.

| S-EPMC3247361 | biostudies-literature

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