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Bis(3-aza-niumylprop-yl)aza-nium hexa-chlorido-bis-muthate(III) monohydrate.

ABSTRACT: The asymmetric unit of the title compound, (C6H20N3)[BiCl6]·H2O, consists of a triprotonated bis-(3-aza-niumylprop-yl)aza-nium cation, two halves of an octahedral [BiCl6](3-) anion, each of the Bi(III) atoms lying on an inversion centre, and a water mol-ecule. In the crystal, the anions and water mol-ecules are linked by O-H⋯Cl hydrogen bonds, forming chains running parallel to [0-11]. The anionic chains and the cations are further linked into a three-dimensional network by N-H⋯Cl and N-H⋯O hydrogen-bond inter-actions.

SUBMITTER: Elfaleh N

PROVIDER: S-EPMC3884999 | biostudies-literature | 2013 Nov

REPOSITORIES: biostudies-literature

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Bis(3-aza-niumylprop-yl)aza-nium hexa-chlorido-bis-muthate(III) monohydrate.

Elfaleh Nizar N Chouaib Hassen H Kamoun Slaheddine S

Acta crystallographica. Section E, Structure reports online 20131116 Pt 12

The asymmetric unit of the title compound, (C6H20N3)[BiCl6]·H2O, consists of a triprotonated bis-(3-aza-niumylprop-yl)aza-nium cation, two halves of an octahedral [BiCl6](3-) anion, each of the Bi(III) atoms lying on an inversion centre, and a water mol-ecule. In the crystal, the anions and water mol-ecules are linked by O-H⋯Cl hydrogen bonds, forming chains running parallel to [0-11]. The anionic chains and the cations are further linked into a three-dimensional network by N-H⋯Cl and N-H⋯O hydr ...[more]

PMID: 24454174

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2,5-Bis[2-({bis-[3-(dimethyl-aza-nium-yl)prop-yl]aza-nium-yl}meth-yl)phen-yl]-1,3,4-oxadiazole hexa-kis-(perchlorate) sesquihydrate.

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