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Tetra-carbonyl-bis(?-cyclo-penta-dienyl)bis[(dec-9-en-1-yl)diphenyl-phosphine]dimolybdenum(0)(Mo-Mo) tetra-hydro-furan disolvate.

ABSTRACT: The asymmetric unit of the title compound, [Mo(2)(?(5)-C(5)H(5))(2)(C(22)H(29)P)(2)(CO)(4)]·2C(4)H(8)O, contains two half-mol-ecules of the organometallic species and two solvent mol-ecules. Both organometallic mol-ecules are completed by crystallographic inversion symmetry, yielding dimeric units with Mo-Mo single-bond lengths of 3.2703?(6) and 3.2548?(6)?Å. Each Mo atom is also coordinated by an ?(5)-cyclo-pentdienyl ligand, two carbonyl ligands, and a (dec-9-en-1-yl)diphenyl-phosphine ligand.

SUBMITTER: Shultz G

PROVIDER: S-EPMC2971763 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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Tetra-carbonyl-bis(η-cyclo-penta-dienyl)bis[(dec-9-en-1-yl)diphenyl-phosphine]dimolybdenum(0)(Mo-Mo) tetra-hydro-furan disolvate.

Shultz Ginger G Zakharov Lev N LN Tyler David R DR

Acta crystallographica. Section E, Structure reports online 20091111 Pt 12

The asymmetric unit of the title compound, [Mo(2)(η(5)-C(5)H(5))(2)(C(22)H(29)P)(2)(CO)(4)]·2C(4)H(8)O, contains two half-mol-ecules of the organometallic species and two solvent mol-ecules. Both organometallic mol-ecules are completed by crystallographic inversion symmetry, yielding dimeric units with Mo-Mo single-bond lengths of 3.2703 (6) and 3.2548 (6) Å. Each Mo atom is also coordinated by an η(5)-cyclo-pentdienyl ligand, two carbonyl ligands, and a (dec-9-en-1-yl)diphenyl-phosphine ligand. ...[more]

PMID: 21578585

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