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ABSTRACT:
SUBMITTER: Dugan TR
PROVIDER: S-EPMC3993920 | biostudies-literature | 2014 Mar
REPOSITORIES: biostudies-literature
Dugan Thomas R TR Bill Eckhard E MacLeod K Cory KC Brennessel William W WW Holland Patrick L PL
Inorganic chemistry 20140220 5
Very few hydride complexes are known in which the metals have a high-spin electronic configuration. We describe the characterization of several high-spin iron(II) hydride/deuteride isotopologues and their exchange reactions with one another and with H2/D2. Though the hydride/deuteride signal is not observable in NMR spectra, the choice of isotope has an influence on the chemical shifts of distant protons in the dimers through the paramagnetic isotope effect on chemical shift. This provides the f ...[more]