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(Cyanido-?C)(2,2-di-phenyl-acetamido-?(2) N,O)bis-(?(5)-penta-methyl-cyclo-penta-dien-yl)zirconium(IV).

ABSTRACT: In the title compound, [Zr(C10H15)2(C14H12NO)(CN)], the Zr(IV) atom is coordinated by two penta-methyl-cyclo-penta-dienyl ligands, the amidate ligand via the N and O atoms, and an additional C N ligand. The four-membered metallacycle is nearly planar (r.m.s. deviation = 0.008?Å). In the crystal, the mol-ecules are connected into centrosymmetric dimers via pairs of N-H?N hydrogen bonds.

SUBMITTER: Becker L

PROVIDER: S-EPMC3998262 | biostudies-literature | 2014 Feb

REPOSITORIES: biostudies-literature

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(Cyanido-κC)(2,2-di-phenyl-acetamido-κ(2) N,O)bis-(η(5)-penta-methyl-cyclo-penta-dien-yl)zirconium(IV).

Becker Lisanne L Spannenberg Anke A Arndt Perdita P Rosenthal Uwe U

Acta crystallographica. Section E, Structure reports online 20140122 Pt 2

In the title compound, [Zr(C10H15)2(C14H12NO)(CN)], the Zr(IV) atom is coordinated by two penta-methyl-cyclo-penta-dienyl ligands, the amidate ligand via the N and O atoms, and an additional C N ligand. The four-membered metallacycle is nearly planar (r.m.s. deviation = 0.008 Å). In the crystal, the mol-ecules are connected into centrosymmetric dimers via pairs of N-H⋯N hydrogen bonds. ...[more]

PMID: 24764823

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