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1-(2,3-Di-methyl-phen-yl)piperazine-1,4-diium tetra-chlorido-cuprate(II).

ABSTRACT: In the title salt, (C12H20N2)[CuCl4], the Cu(II) atom occupies a general position in a flattened tetra-hedral environment by Cl ligands, characterized by Cl-Cu-Cl angles of 134.04?(3) and 137.18?(4)°. The six-membered piperazinediium ring adopts a chair conformation. The organic cation and inorganic anion inter-act through N-H?Cl and C-H?Cl hydrogen bonds, forming a three-dimensional network.

SUBMITTER: Ben Mabrouk S 

PROVIDER: S-EPMC3884381 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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1-(2,3-Di-methyl-phen-yl)piperazine-1,4-diium tetra-chlorido-cuprate(II).

Ben Mabrouk Safa S   Ameur Iness I   Abid Sonia S   Rzaigui Mohamed M  

Acta crystallographica. Section E, Structure reports online 20130810 Pt 9

In the title salt, (C12H20N2)[CuCl4], the Cu(II) atom occupies a general position in a flattened tetra-hedral environment by Cl ligands, characterized by Cl-Cu-Cl angles of 134.04 (3) and 137.18 (4)°. The six-membered piperazinediium ring adopts a chair conformation. The organic cation and inorganic anion inter-act through N-H⋯Cl and C-H⋯Cl hydrogen bonds, forming a three-dimensional network. ...[more]

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