Ontology highlight
ABSTRACT:
SUBMITTER: Li AH
PROVIDER: S-EPMC4051072 | biostudies-literature | 2014 Jun
REPOSITORIES: biostudies-literature
Li Ai-Hong AH Han Jun-Ping JP Li Jing J
Acta crystallographica. Section E, Structure reports online 20140521 Pt 6
The asymmetric unit of the title compound, [Li2(C12H12NOP)6]Cl2·2CH3CN, contains one-half of the centrosymmetric dication, one chloride anion and one aceto-nitrile solvent mol-ecule. Each Li atom is coordinated by four O atoms [Li-O 1.891 (3) and 2.025 (3) Å] from the four di-phenyl-phosphinamide ligands in a distorted tetra-hedral geometry. In the crystal, weak N-H⋯Cl hydrogen bonds link the anions and dications into columns extending along [100]. ...[more]