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Aerobic oxidation in nanomicelles of aryl alkynes, in water at room temperature.

ABSTRACT: On the basis of the far higher solubility of oxygen gas inside the hydrocarbon core of nanomicelles, metal and peroxide free aerobic oxidation of aryl alkynes to ?-ketosulfones has been achieved in water at room temperature. Many examples are offered that illustrate broad functional group tolerance. The overall process is environmentally friendly, documented by the associated low E Factors.

SUBMITTER: Handa S

PROVIDER: S-EPMC4076018 | biostudies-literature | 2014 Mar

REPOSITORIES: biostudies-literature

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Aerobic oxidation in nanomicelles of aryl alkynes, in water at room temperature.

Handa Sachin S Fennewald James C JC Lipshutz Bruce H BH

Angewandte Chemie (International ed. in English) 20140224 13

On the basis of the far higher solubility of oxygen gas inside the hydrocarbon core of nanomicelles, metal and peroxide free aerobic oxidation of aryl alkynes to β-ketosulfones has been achieved in water at room temperature. Many examples are offered that illustrate broad functional group tolerance. The overall process is environmentally friendly, documented by the associated low E Factors. ...[more]

PMID: 24616243

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