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Tetra-amminepalladium(II) dichloride ammonia tetra-solvate.

ABSTRACT: The title compound, [Pd(NH3)4]Cl2·4NH3, was crystallized in liquid ammonia from the salt Pd(en)Cl2 (en is ethylenediamine) and is isotypic with [Pt(NH3)4]Cl2·4NH3 [Grassl & Korber (2014 ?). Acta Cryst. E70, i31]. The Pd(2+) cation is coordinated by four ammonia mol-ecules, exhibiting a square-planar geometry. The chloride anions are surrounded by nine ammonia mol-ecules. These are either bound in the palladium complex or solvent mol-ecules. The packing of the ammonia solvent mol-ecules enables the formation of an extended network of N-H?N and N-H?Cl inter-actions with nearly ideal hydrogen-bonding geometry.

SUBMITTER: Grassl T

PROVIDER: S-EPMC4120636 | biostudies-literature | 2014 Jul

REPOSITORIES: biostudies-literature

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Tetra-amminepalladium(II) dichloride ammonia tetra-solvate.

Grassl Tobias T Korber Nikolaus N

Acta crystallographica. Section E, Structure reports online 20140607 Pt 7

The title compound, [Pd(NH3)4]Cl2·4NH3, was crystallized in liquid ammonia from the salt Pd(en)Cl2 (en is ethylenediamine) and is isotypic with [Pt(NH3)4]Cl2·4NH3 [Grassl & Korber (2014 ▶). Acta Cryst. E70, i31]. The Pd(2+) cation is coordinated by four ammonia mol-ecules, exhibiting a square-planar geometry. The chloride anions are surrounded by nine ammonia mol-ecules. These are either bound in the palladium complex or solvent mol-ecules. The packing of the ammonia solvent mol-ecules enables t ...[more]

PMID: 25161505

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