Ontology highlight
ABSTRACT:
SUBMITTER: Yang Y
PROVIDER: S-EPMC4127133 | biostudies-literature | 2014 Aug
REPOSITORIES: biostudies-literature
Yang Yang Y Buchwald Stephen L SL
Angewandte Chemie (International ed. in English) 20140506 33
A copper-based catalytic technique for the regioselective ortho C-H cyanation of vinylarenes has been developed. This method provides an effective means for the selective functionalization of vinylarene derivatives. A copper-catalyzed cyanative dearomatization mechanism is proposed to account for the regiochemical course of this reaction. ...[more]