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Stereoretentive Pd-catalyzed Kumada-Corriu couplings of alkenyl halides at room temperature.


ABSTRACT: Stereoselective palladium-catalyzed Kumada-Corriu reactions of functionalized alkenyl halides and a variety of Grignard reagents, including those bearing ?-hydrogen atoms and sensitive functional groups, can be carried out at room temperature using a new combination of reagents.

SUBMITTER: Krasovskiy AL 

PROVIDER: S-EPMC4136712 | biostudies-literature | 2014 Aug

REPOSITORIES: biostudies-literature

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Stereoretentive Pd-catalyzed Kumada-Corriu couplings of alkenyl halides at room temperature.

Krasovskiy Arkady L AL   Haley Stephen S   Voigtritter Karl K   Lipshutz Bruce H BH  

Organic letters 20140807 16


Stereoselective palladium-catalyzed Kumada-Corriu reactions of functionalized alkenyl halides and a variety of Grignard reagents, including those bearing β-hydrogen atoms and sensitive functional groups, can be carried out at room temperature using a new combination of reagents. ...[more]

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