Unknown

Dataset Information

0

Highly selective reactions of unbiased alkenyl halides and alkylzinc halides: Negishi-Plus couplings.

ABSTRACT: High yielding stereo- and chemoselective Pd-catalyzed cross-couplings in THF at room temperature of alkenyl iodides and bromides with primary and secondary alkyl zinc iodides have been developed with the aid of N-methyimidazole as the key additive.

SUBMITTER: Krasovskiy A 

PROVIDER: S-EPMC3365517 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Highly selective reactions of unbiased alkenyl halides and alkylzinc halides: Negishi-Plus couplings.

Krasovskiy Arkady A   Lipshutz Bruce H BH  

Organic letters 20110708 15

High yielding stereo- and chemoselective Pd-catalyzed cross-couplings in THF at room temperature of alkenyl iodides and bromides with primary and secondary alkyl zinc iodides have been developed with the aid of N-methyimidazole as the key additive. ...[more]

Similar Datasets

Unknown Ligand effects on Negishi couplings of alkenyl halides.
| S-EPMC3365518 | biostudies-other
Unknown Nickel-catalyzed Negishi cross-coupling reactions of secondary alkylzinc halides and aryl iodides.
| S-EPMC6474776 | biostudies-literature
Unknown Stereoselective Negishi-like couplings between alkenyl and alkyl halides in water at room temperature.
| S-EPMC3365513 | biostudies-literature
Unknown Stereoselective Csp3 -Csp2 Cross-Couplings of Chiral Secondary Alkylzinc Reagents with Alkenyl and Aryl Halides.
| S-EPMC6973128 | biostudies-literature
Unknown Negishi coupling of secondary alkylzinc halides with aryl bromides and chlorides.
| S-EPMC2746668 | biostudies-literature
Unknown Highly selective palladium-catalyzed cross-coupling of secondary alkylzinc reagents with heteroaryl halides.
| S-EPMC4156254 | biostudies-literature
Unknown Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction.
| S-EPMC5531279 | biostudies-literature
Unknown Catalytic enantioselective cross-couplings of secondary alkyl electrophiles with secondary alkylmetal nucleophiles: Negishi reactions of racemic benzylic bromides with achiral alkylzinc reagents.
| S-EPMC3474870 | biostudies-literature
Unknown "On water" sp3-sp2 cross-couplings between benzylic and alkenyl halides.
| S-EPMC3352766 | biostudies-other
Unknown Stereoretentive Pd-catalyzed Kumada-Corriu couplings of alkenyl halides at room temperature.
| S-EPMC4136712 | biostudies-literature