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Crystal structure of bis-{N-[2-(di-methyl-amino)-eth-yl]quinolin-8-amine-?(3) N,N',N''}nickel(II) dichloride 3.5-hydrate.

ABSTRACT: In the title compound, [Ni(C13H17N3)2]Cl2·3.5H2O, the geom-etry of the NiN6 complex cation is slightly distorted octa-hedral, with a facial arrangement of the two tridentate N-[2-(di--methyl-amino)-eth-yl]quinolin-8-amine ligands around the metal ion. The asymmetric unit consists of two independent complex half-mol-ecules located on centres of inversion, together with two chloride counter-anions and 3.5 water mol-ecules of solvation, one of which is disordered across an inversion centre. In the crystal, O-H?O, O-H?Cl and N-H?Cl hydrogen-bonding inter-actions form a three-dimensional network structure.

SUBMITTER: Kariuki BM

PROVIDER: S-EPMC4186116 | biostudies-literature | 2014 Sep

REPOSITORIES: biostudies-literature

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Crystal structure of bis-{N-[2-(di-methyl-amino)-eth-yl]quinolin-8-amine-κ(3) N,N',N''}nickel(II) dichloride 3.5-hydrate.

Kariuki Benson M BM Al-Sudani Abdul-Razak H AR

Acta crystallographica. Section E, Structure reports online 20140830 Pt 9

In the title compound, [Ni(C13H17N3)2]Cl2·3.5H2O, the geom-etry of the NiN6 complex cation is slightly distorted octa-hedral, with a facial arrangement of the two tridentate N-[2-(di--methyl-amino)-eth-yl]quinolin-8-amine ligands around the metal ion. The asymmetric unit consists of two independent complex half-mol-ecules located on centres of inversion, together with two chloride counter-anions and 3.5 water mol-ecules of solvation, one of which is disordered across an inversion centre. In the ...[more]

PMID: 25309190

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