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Crystal structure of N (1)-benzyl-N (1),N (2),N (2)-tri-methyl-ethane-1,2-diaminium dichloride.

ABSTRACT: In the title mol-ecular salt, C12H22N2 (2+)·2Cl(-), which was obtained as a by-product in the attempted synthesis of a mercury derivative, the conformation of the N-C-C-N bond in the cation is anti [torsion angle = 175.1?(10)°]. In the crystal, the cations are linked to the anions by N-H?Cl hydrogen bonds, generating ion-triplets. These are linked by numerous weak C-H?Cl inter-actions, generating a three-dimensional network. The structure was refined as an inversion twin.

SUBMITTER: Singh P

PROVIDER: S-EPMC4186135 | biostudies-literature | 2014 Sep

REPOSITORIES: biostudies-literature

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Crystal structure of N (1)-benzyl-N (1),N (2),N (2)-tri-methyl-ethane-1,2-diaminium dichloride.

Singh Pushpendra P Singh Harkesh B HB Butcher Ray J RJ

Acta crystallographica. Section E, Structure reports online 20140801 Pt 9

In the title mol-ecular salt, C12H22N2 (2+)·2Cl(-), which was obtained as a by-product in the attempted synthesis of a mercury derivative, the conformation of the N-C-C-N bond in the cation is anti [torsion angle = 175.1 (10)°]. In the crystal, the cations are linked to the anions by N-H⋯Cl hydrogen bonds, generating ion-triplets. These are linked by numerous weak C-H⋯Cl inter-actions, generating a three-dimensional network. The structure was refined as an inversion twin. ...[more]

PMID: 25309248

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