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Crystal structure of N,N'-bis-(diiso-propyl-phosphan-yl)-4-methyl-pyridine-2,6-di-amine.

ABSTRACT: In the mol-ecule of the title compound, C18H35N3P2, the methyl-pyridine-2,6-di-amine moiety is almost planar, with a maximum deviation of 0.0129?(9)?Å for one of the amine N atoms. Whereas one of the P atoms is co-planar with this mean plane [deviation = 0.0158?(10)?Å], the other P atom is considerably displaced out of the mean plane by 0.5882?(10)?Å. In the crystal, no directional intermolecular interactions beyond van der Waals contacts could be identified.

SUBMITTER: Stoger B

PROVIDER: S-EPMC4186153 | biostudies-literature | 2014 Sep

REPOSITORIES: biostudies-literature

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Crystal structure of N,N'-bis-(diiso-propyl-phosphan-yl)-4-methyl-pyridine-2,6-di-amine.

Stöger Berthold B Weil Matthias M Bichler Bernhard B Eder Wolfgang W Kirchner Karl K

Acta crystallographica. Section E, Structure reports online 20140801 Pt 9

In the mol-ecule of the title compound, C18H35N3P2, the methyl-pyridine-2,6-di-amine moiety is almost planar, with a maximum deviation of 0.0129 (9) Å for one of the amine N atoms. Whereas one of the P atoms is co-planar with this mean plane [deviation = 0.0158 (10) Å], the other P atom is considerably displaced out of the mean plane by 0.5882 (10) Å. In the crystal, no directional intermolecular interactions beyond van der Waals contacts could be identified. ...[more]

PMID: 25309237

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[Bis(2,6-diiso-propyl-phen-yl) phosphato-κ<i>O</i>]pentakis-(methanol-κ<i>O</i>)manganese bis-(2,6-diiso-propyl-phen-yl) phosphate methanol tris-olvate.

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