Unknown

Dataset Information

0

Crystal structures of bis-[2-(di-phenyl-phosphino-thio-yl)phen-yl] ether and bis-{2-[diphen-yl(selanyl-idene)phosphan-yl]phen-yl} ether.

ABSTRACT: The title compounds, C36H28OP2S2, (1), and C36H28OP2Se2, (2), exhibit remarkably similar structures although they are not isomorphous. The whole mol-ecule of compound (2) is generated by twofold symmetry, with the ether O atom located on the twofold axis. Both compounds have intra-molecular ?-? inter-actions between terminal phenyl rings with centroid-centroid distances of 3.6214?(16) and 3.8027?(14)?Å in (1) and (2), respectively. In the crystal of (1), short C-H?S hydrogen bonds link the mol-ecules, forming chains along [001], while in (2) there are no analogous C-H?Se inter-actions present.

SUBMITTER: Janzen DE 

PROVIDER: S-EPMC4257402 | biostudies-literature | 2014 Dec

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Crystal structures of bis-[2-(di-phenyl-phosphino-thio-yl)phen-yl] ether and bis-{2-[diphen-yl(selanyl-idene)phosphan-yl]phen-yl} ether.

Janzen Daron E DE   Kooyman Arianna M AM   Lange Kayla A KA  

Acta crystallographica. Section E, Structure reports online 20141119 Pt 12

The title compounds, C36H28OP2S2, (1), and C36H28OP2Se2, (2), exhibit remarkably similar structures although they are not isomorphous. The whole mol-ecule of compound (2) is generated by twofold symmetry, with the ether O atom located on the twofold axis. Both compounds have intra-molecular π-π inter-actions between terminal phenyl rings with centroid-centroid distances of 3.6214 (16) and 3.8027 (14) Å in (1) and (2), respectively. In the crystal of (1), short C-H⋯S hydrogen bonds link the mol-e  ...[more]

Similar Datasets

Unknown Bis[4-(2-benzyl-idenepropyl-idene-amino)phen-yl] ether.
| S-EPMC2968496 | biostudies-literature
Unknown Bis(1-{bis-[2-(diphenyl-phosphino-yl)eth-yl]phosphan-yl}-2-(diphenyl-phosphan-yl)ethane)dinitratoplatinum(II) methanol tetra-solvate.
| S-EPMC2961811 | biostudies-literature
Unknown Bis[bis-(2-methyl-phen-yl)phosphan-yl]methane.
| S-EPMC3051801 | biostudies-literature
Unknown (2-{[2-(diphenyl-phosphino)phen-yl]thio}-phen-yl)diphenyl-phosphine sulfide.
| S-EPMC3515196 | biostudies-literature
Unknown 1,5-Bis[1-(4-bromo-phen-yl)ethyl-idene]thio-carbonohydrazide.
| S-EPMC3648255 | biostudies-literature
Unknown trans-Dichloridobis[diphen-yl(thio-phen-2-yl)phosphane-?P]palladium(II).
| S-EPMC3344332 | biostudies-literature
Unknown 1,2-Bis{bis-[4-(trifluoro-meth-yl)phen-yl]phosphino}ethane.
| S-EPMC2960220 | biostudies-literature
Unknown 1,5-Bis[1-(4-meth-oxy-phen-yl)ethyl-idene]thio-carbonohydrazide.
| S-EPMC3213572 | biostudies-literature
Unknown 1,1'-Bis[bis-(4-meth-oxy-phen-yl)phosphan-yl]ferrocene.
| S-EPMC3393188 | biostudies-literature
Unknown Chlorido{N-[(E)-2-(diphenyl-phosphan-yl)benzyl-idene]-2-(thio-phen-2-yl)ethan-amine-?P}gold(I).
| S-EPMC3254317 | biostudies-literature