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Crystal structure of piperidinium 4-nitro-phenolate.

ABSTRACT: In the title mol-ecular salt, C5H12N(+)·C6H4NO3 (-), the piperidine ring adopts a chair conformation and the cation is protonated at the N atom. In the anion, the nitro group is twisted at an angle of 10.30?(11)° with respect to the attached benzene ring. In the crystal, N-H?O hydrogen bonds link adjacent anions and cations into infinite chains propagating along [100]. The chains are linked by C-H?? inter-actions, forming sheets lying parallel to (001).

SUBMITTER: Sowmya NS

PROVIDER: S-EPMC4257431 | biostudies-literature | 2014 Dec

REPOSITORIES: biostudies-literature

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Crystal structure of piperidinium 4-nitro-phenolate.

Sowmya N Swarna NS Sampathkrishnan S S Sudhahar S S Chakkaravarthi G G Kumar R Mohan RM

Acta crystallographica. Section E, Structure reports online 20141121 Pt 12

In the title mol-ecular salt, C5H12N(+)·C6H4NO3 (-), the piperidine ring adopts a chair conformation and the cation is protonated at the N atom. In the anion, the nitro group is twisted at an angle of 10.30 (11)° with respect to the attached benzene ring. In the crystal, N-H⋯O hydrogen bonds link adjacent anions and cations into infinite chains propagating along [100]. The chains are linked by C-H⋯π inter-actions, forming sheets lying parallel to (001). ...[more]

PMID: 25552992

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