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Dimethyl-ammonium 4-nitro-phenolate-4-nitro-phenol (1/1).

ABSTRACT: The title compound, C(2)H(8)N(+)·C(6)H(4)NO(3) (-)·C(6)H(5)NO(3), was synthesized from dimethyl-amine and 4-nitro-phenol in an overall yield of 85%. The dihdral angles between the nphenyl rings and their attached nitro groups are 5.7?(6) and 2.5?(7)°. In the crystal, there are strong hydrogen bonds between the ammonium group and the nitro-phenol and nitro-phenolate O atoms, and between the nitro-phenol and nitro-phenolate O atoms, forming a chain along the b-axis direction.

SUBMITTER: Xiao JM

PROVIDER: S-EPMC2984031 | biostudies-literature | 2010 Mar

REPOSITORIES: biostudies-literature

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Dimethyl-ammonium 4-nitro-phenolate-4-nitro-phenol (1/1).

Xiao Jing-Mei JM

Acta crystallographica. Section E, Structure reports online 20100310 Pt 4

The title compound, C(2)H(8)N(+)·C(6)H(4)NO(3) (-)·C(6)H(5)NO(3), was synthesized from dimethyl-amine and 4-nitro-phenol in an overall yield of 85%. The dihdral angles between the nphenyl rings and their attached nitro groups are 5.7 (6) and 2.5 (7)°. In the crystal, there are strong hydrogen bonds between the ammonium group and the nitro-phenol and nitro-phenolate O atoms, and between the nitro-phenol and nitro-phenolate O atoms, forming a chain along the b-axis direction. ...[more]

PMID: 21580630

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