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Crystal structure of bis-(2-{[(3-bromo-prop-yl)imino]-meth-yl}phenolato-?(2) N,O)copper(II).

ABSTRACT: In the title compound, [Cu(C10H11BrNO)2], the asymmetric unit consists of one-half of the mol-ecule, the other half being generated by an inversion centre. Hence the Cu(II) cation is symmetrically coordinated by two bidentate Schiff base anions in a slightly distorted square-planar environment with Cu-O and Cu-N bond lengths of 1.8786?(19) and 2.009?(2)?Å, respectively. In the crystal, individual mol-ecules are packed in alternating zigzag layers parallel to (001). Weak C-H?? inter-actions exist between the mol-ecules.

SUBMITTER: Ourari A

PROVIDER: S-EPMC4384597 | biostudies-literature | 2015 Feb

REPOSITORIES: biostudies-literature

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Crystal structure of bis-(2-{[(3-bromo-prop-yl)imino]-meth-yl}phenolato-κ(2) N,O)copper(II).

Ourari Ali A Zoubeidi Chahinaz C Bouacida Sofiane S Derafa Wassila W Merazig Hocine H

Acta crystallographica. Section E, Crystallographic communications 20150124 Pt 2

In the title compound, [Cu(C10H11BrNO)2], the asymmetric unit consists of one-half of the mol-ecule, the other half being generated by an inversion centre. Hence the Cu(II) cation is symmetrically coordinated by two bidentate Schiff base anions in a slightly distorted square-planar environment with Cu-O and Cu-N bond lengths of 1.8786 (19) and 2.009 (2) Å, respectively. In the crystal, individual mol-ecules are packed in alternating zigzag layers parallel to (001). Weak C-H⋯π inter-actions exist ...[more]

PMID: 25878842

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