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Bis{4-bromo-2-[(naphthalen-1-yl-imino)-meth-yl]phenolato-?N,O}copper(II).

ABSTRACT: The title complex, [Cu(C(17)H(11)BrNO)(2)], lies on a centre of inversion. The chelating Schiff base anions define a square-planar N(2)O(2) donor set. The nearly perpendicular orientation of the naphthyl residues of the chelate ring [dihedral angle = 82.12?(12)°] precludes the Cu(II) centre from additional coordination. In the refinement, the naphthyl rings were found to be disordered over two positions.; the major component has a site occupancy of 0.667?(4).

SUBMITTER: Shahverdizadeh GH

PROVIDER: S-EPMC3297236 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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Bis{4-bromo-2-[(naphthalen-1-yl-imino)-meth-yl]phenolato-κN,O}copper(II).

Shahverdizadeh Gholam Hossein GH Ng Seik Weng SW Tiekink Edward R T ER Mirtamizdoust Babak B

Acta crystallographica. Section E, Structure reports online 20120210 Pt 3

The title complex, [Cu(C(17)H(11)BrNO)(2)], lies on a centre of inversion. The chelating Schiff base anions define a square-planar N(2)O(2) donor set. The nearly perpendicular orientation of the naphthyl residues of the chelate ring [dihedral angle = 82.12 (12)°] precludes the Cu(II) centre from additional coordination. In the refinement, the naphthyl rings were found to be disordered over two positions.; the major component has a site occupancy of 0.667 (4). ...[more]

PMID: 22412426

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