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Crystal structure of bis-(thio-urea-?S)bis-(tri-phenylphosphane-?P)silver(I) nitrate.

ABSTRACT: In the title salt, [Ag(CH4N2S)2(PPh3)2]NO3, the Ag(I) atom is coordinated by two thio-urea S atoms and two tri-phenyl-phosphane P atoms in a distorted tetra-hedral geometry, with bond angles in the range 102.90?(4)-123.29?(4)°. The Ag-S=C bond angles are 101.75?(19) and 111.29?(18)°. In the crystal, the component ions are linked by C-H?O, C-H?S, N-H?O and N-H?S hydrogen bonds, generating (10-1) sheets.

SUBMITTER: Nawaz S

PROVIDER: S-EPMC4384606 | biostudies-literature | 2015 Feb

REPOSITORIES: biostudies-literature

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Crystal structure of bis-(thio-urea-κS)bis-(tri-phenylphosphane-κP)silver(I) nitrate.

Nawaz Sidra S Tahir Muhammad Nawaz MN Nadeem Muhammad Amir MA Mehmood Bushra B Ahmad Saeed S

Acta crystallographica. Section E, Crystallographic communications 20150128 Pt 2

In the title salt, [Ag(CH4N2S)2(PPh3)2]NO3, the Ag(I) atom is coordinated by two thio-urea S atoms and two tri-phenyl-phosphane P atoms in a distorted tetra-hedral geometry, with bond angles in the range 102.90 (4)-123.29 (4)°. The Ag-S=C bond angles are 101.75 (19) and 111.29 (18)°. In the crystal, the component ions are linked by C-H⋯O, C-H⋯S, N-H⋯O and N-H⋯S hydrogen bonds, generating (10-1) sheets. ...[more]

PMID: 25878824

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