(N,N'-Di-ethyl-thio-urea-?S)tris-(triphenylphosphane-?P)silver(I) acetate methanol monosolvate.

ABSTRACT: In the mononuclear title complex, [Ag(C5H12N2S)(C18H15P)3](CH3COO)·CH3OH, the Ag(I) ion is in a distorted tetra-hedral coordination geometry formed by three P atoms from three tri-phenyl-phosphane ligands and one S atom from an N,N'-di-ethyl-thio-urea ligand. In the crystal, the acetate anion is connected to the complex mol-ecule via a pair of N-H?O hydrogen bonds [graph-set motif R (2) 2(8)] and the solvent methanol mol-ecule is connected to the anion via an O-H?O hydrogen bond. This aggregate is further connected through a weak C-H?O hydrogen bond, forming a chain along [100]. In addition, sixfold phenyl embraces with inter-molecular distances of 6.6463?(13)-6.667?(2)?Å are arranged in a chain along [001]. The combination of hydrogen bonding and phen-yl?phenyl inter-actions leads to the formation of a two-dimensional network parallel to (010).

SUBMITTER: Wattanakanjana Y 

PROVIDER: S-EPMC4051053 | biostudies-literature | 2014 Jun

REPOSITORIES: biostudies-literature