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Ligand-enabled cross-coupling of C(sp(3))-H bonds with arylsilanes.


ABSTRACT: Pd(II)-catalyzed cross-coupling of C(sp(3))-H bonds with organosilicon coupling partners has been achieved for the first time. The use of a newly developed quinoline-based ligand is essential for the cross-coupling reactions to proceed.

SUBMITTER: He J 

PROVIDER: S-EPMC4432906 | biostudies-literature | 2015 Apr

REPOSITORIES: biostudies-literature

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Ligand-enabled cross-coupling of C(sp(3))-H bonds with arylsilanes.

He Jian J   Takise Ryosuke R   Fu Haiyan H   Yu Jin-Quan JQ  

Journal of the American Chemical Society 20150402 14


Pd(II)-catalyzed cross-coupling of C(sp(3))-H bonds with organosilicon coupling partners has been achieved for the first time. The use of a newly developed quinoline-based ligand is essential for the cross-coupling reactions to proceed. ...[more]

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