Ontology highlight
ABSTRACT:
SUBMITTER: Monopoli A
PROVIDER: S-EPMC4505175 | biostudies-literature | 2015
REPOSITORIES: biostudies-literature
Beilstein journal of organic chemistry 20150610
The Pd-benzothiazol-2-ylidene complex I was found to be a chemoselective catalyst for the Tsuji-Trost allylation of active methylene compounds carried out under neutral conditions and using carbonates as allylating agents. The proposed protocol consists in a simplified procedure adopting an in situ prepared catalyst from Pd2dba3 and 3-methylbenzothiazolium salt V as precursors. A comparison of the performance of benzothiazole carbene with phosphanes and an analogous imidazolium carbene ligand is ...[more]