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Spectroscopic tracking of molecular transport junctions generated by using click chemistry.


ABSTRACT: Click to fill the gap: The in situ modular fabrication of molecular transport junctions in nanogaps generated by on-wire lithography is achieved by using click chemistry (see picture). The formation of molecular junctions proceeds in high yields and can be used to test different molecules; the triazole group also maintains conjugation in the molecular wires. Raman spectroscopy is used to characterize the molecular assembly processes.

SUBMITTER: Chen X 

PROVIDER: S-EPMC4507743 | biostudies-literature | 2009

REPOSITORIES: biostudies-literature

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Spectroscopic tracking of molecular transport junctions generated by using click chemistry.

Chen Xiaodong X   Braunschweig Adam B AB   Wiester Michael J MJ   Yeganeh Sina S   Ratner Mark A MA   Mirkin Chad A CA  

Angewandte Chemie (International ed. in English) 20090101 28


Click to fill the gap: The in situ modular fabrication of molecular transport junctions in nanogaps generated by on-wire lithography is achieved by using click chemistry (see picture). The formation of molecular junctions proceeds in high yields and can be used to test different molecules; the triazole group also maintains conjugation in the molecular wires. Raman spectroscopy is used to characterize the molecular assembly processes. ...[more]

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