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(?-Ethane-1,2-diamine-?N:N')bis-[dicarbon-yl(?-cyclo-penta-dien-yl)iron(II)] bis-(tetra-fluorido-borate).

ABSTRACT: The asymmetric unit of the title compound, [Fe(2)(C(5)H(5))(2)(C(2)H(8)N(2))(CO)(4)](BF(4))(2), contains two half-cations, each located on a center of symmetry, and two tetra-fluorido-borate anions. The iron atoms adopt a three-legged piano-stool geometry. All amine H atoms are involved in N-H?F hydrogen bonds, which consolidate the crystal packing along with weak C-H?O and C-H?F inter-actions.

SUBMITTER: M'thiruaine CM 

PROVIDER: S-EPMC3099767 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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(μ-Ethane-1,2-diamine-κN:N')bis-[dicarbon-yl(η-cyclo-penta-dien-yl)iron(II)] bis-(tetra-fluorido-borate).

M'thiruaine Cyprian M CM   Friedrich Holger B HB   Changamu Evans O EO   Omondi Bernard B  

Acta crystallographica. Section E, Structure reports online 20110326 Pt 4

The asymmetric unit of the title compound, [Fe(2)(C(5)H(5))(2)(C(2)H(8)N(2))(CO)(4)](BF(4))(2), contains two half-cations, each located on a center of symmetry, and two tetra-fluorido-borate anions. The iron atoms adopt a three-legged piano-stool geometry. All amine H atoms are involved in N-H⋯F hydrogen bonds, which consolidate the crystal packing along with weak C-H⋯O and C-H⋯F inter-actions. ...[more]

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