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ABSTRACT:
SUBMITTER: Suarez-Pantiga S
PROVIDER: S-EPMC4648034 | biostudies-literature | 2015 Nov
REPOSITORIES: biostudies-literature
Suárez-Pantiga Samuel S Colas Kilian K Johansson Magnus J MJ Mendoza Abraham A
Angewandte Chemie (International ed. in English) 20150904 47
The development of more active C-H oxidation catalysts has inspired a rapid, scalable, and stereoselective assembly of multifunctional piperazines through a [3+3] coupling of azomethine ylides. A combination of visible-light irradiation and aluminum organometallics is essential to promote this transformation, which introduces visible-light photochemistry of main-group organometallics and sets the basis for new and promising catalysts. ...[more]